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[Dan
Berger strikes again in his crusade to educate the wine drinking public. The
Fish
bladders, eggs, copper, milk -- are they really in that bottle of Syrah? They
might have been at some point. Winemaking may be called an art, but there’s
plenty of science involved in the process, and some of the substances thrown in
the tank along the way might surprise you.
Almost
all of this stuff has been removed by the time the wine reaches the bottle, so
what you end up drinking is grapes and little else. But some chemical secrets of
winemakers will be unveiled by the new Food Allergen Labeling and Consumer
Protection Act signed into law in August 2004, by President Bush.
Milk,
eggs, and fish are potential allergens, and each is used in winemaking. All
three are part of a class of substances called fining agents, and in theory all
are completely removed from the wine before bottling. Fining agents are just one
class of chemicals used during the winemaking process to give grape juice a
makeover. Some winemakers also use flavor enhancers and correctors, coloring
agents, and yeast nutrients.
Perhaps
the most famous wine additives are sulfites which concern people enough to
already merit their own warning label. Sulfites are crucial for preventing wine
from spoiling and have been used in some form for centuries. Recent research
appears to acquit sulfites of culpability for “Red Wine Headache Syndrome,”
but some asthmatics may react to their presence.
It
would be nice if vegans, asthmatics, or anyone sensitive to a particular
additive could scan the bottle’s label to see a list of everything that has
gone into making the wine. But until labeling laws change drastically, sensitive
wine drinkers will have to settle for calling the winery for information about
additives. Most people have no reason to think about what might have been in the
wine they’re drinking, and never would think about it except when they’re
prompted to ask, “Hey, what are those things floating in my glass?”
Fining
Agents
Fining agents remove elements that could affect the appearance or texture of the
wine. For example, winemakers seeking to soften the texture of a
highly tannic red wine might add egg whites or gelatin. Fining agents are
added to a tank or barrel of wine. The substance grabs onto whatever solid
matter it has an affinity for, and over a number of days carries it to the
bottom. The wine is then drained off leaving the residue and the fining agent
behind.
Different
fining agents are used for different purposes. Isinglass, an extremely pure
gelatin produced from the bladders of sturgeon, is used mostly in white and
sparkling wines to improve visual clarity and purify aroma. Bentonite, a
volcanic clay, removes proteins for better clarity as well as stability during
long-term storage. Egg whites are used almost routinely in red Bordeaux and are
also used to remove bitterness from Sherry in Jerez, Spain. Once it was common
throughout that district to see Sherry houses separating eggs to use the whipped
whites for fining the wine. What became of the yolks? Restaurants all over the
district would routinely offer dishes with béarnaise and hollandaise sauces!
One
fining agent popular with red-wine makers is a substance similar to ground-up
nylon called polyvinyl polypyrrolidone, PVPP for short. A patented product of
GAF Corp., PVPP is used to remove the pink color from some white wines. Because
it can remove very small molecules, it also helps reduce bitterness. Small
tannins are bitter; larger tannins are less so. Removing the smaller ones is
helpful to keeping a red wine from being bitter.
A new technology
accomplishes the same task in a different way. Vinovation, a Sonoma County
technical consulting firm, uses a patented French process called
micro-oxygenation that helps small tannin molecules clump together. [Fewer,
larger arrays of tannin have much less contact with the mouth than dispersed
molecules because they have less surface area. The resulting wine is perceived
as less tannic.]
Flavor Correctors
The most common addition to wine is acid. Almost all wines in California have
their acid “adjusted,” which is winespeak for an addition of acid to
accommodate for a deficiency. Insufficient acidity makes a wine taste flabby or
flat. Acid additions do not change the aroma of a wine, but can increase
tartness. Most acids supplements are natural, such as tartaric or citric.
Tartaric acid, in
fact, is the strongest and most common naturally occurring acid in wine grapes.
It’s responsible for glass-like crystals, or tartrates, that form in some
chilled bottles, often just under the cork. While completely harmless, the
crystals taste as tart as the acid they come from. They’re often removed in
the winemaking process, mostly for visual effect, and some wineries collect and
sell them to companies that make cream of tartar which is used to help cake
rise.
A few winemakers also
use trace amounts of ascorbic acid (vitamin C) in some early-drinking white
wines. It acts as an oxygen scavenger and keeps the wine fresher. What if a wine
is already too tart? Some winemakers add potassium bitartrate which does the
trick.
Consumers love the
flavors of vanilla and wood that come from oak barrels. But new oak barrels are
expensive, so makers of inexpensive wines sometimes take a shortcut, adding oak
chips or even powder to a wine being made in a cheaper container. The oak is
removed before bottling, but that oaky flavor remains.
Flawed wines can
sometimes be “rescued.” Wines that have developed hydrogen sulfide (H2S),
and thus are termed “reduced,” can have a rotten egg smell. Copper sulfate
is a common solution to deal with H2S. The copper reacts with the H2S to
eliminate the stink. Copper has its drawbacks because it is also an oxidation
catalyst and can shorten the life of a red wine.
But copper can be the
consumer’s friend. When you get a wine that has a slight hint of that rotten
egg smell, drop a penny into the glass and after a minute or two the H2S smell
should drop or be wiped out. Old pennies have more copper than newer ones and
work better.
Coloring Agents
For years, dark Petite Sirah and Alicante Bouschet were routinely added to
pale-colored red wines. They, however, add flavors of their own, and even as
little as 2 percent can sometimes dominate the taste of a more delicate varietal.
Over the last decade, a number of companies have developed stable color additives, including one introduced in 2001 by Canandaigua Concentrate, a division of the wine company of the same name. Called MegaNatural, the substance is derived from grape skins and, according to the company, “can be custom-formulated into a wide range of shades of red, including Pink Grapefruit, Strawberry, Cranberry Red, Cherry, Raspberry, and the variations in-between.”
Yeast Nutrients
Yeast is essential in the winemaking process, for it converts the sugar in the
grapes to alcohol. If the yeast dies off before fermentation is complete, the
remaining sugar will make the wine sweet, like a dessert wine. Yeast nutrients
-- the most common is diamonium phosphate, a nitrogen source -- contain vitamins
and amino acids that keep yeasts healthy so a wine can completely ferment to
dryness.
“The best tactic,” said Clark
Smith, winemaker and president of Vinovation, “is to have healthy fruit come
in, and that means grapes picked at moderate sugars. Well-balanced grapes
normally contain all the nutrition that a healthy fermentation needs. It’s
when you get underripe or very ripe fruit that you run into problems.”
Preservatives
Like all food products, wine can be made without preservatives. But while the
idea is appealing, the reality is a problem for a product that people routinely
store for a decade or more before consuming.
Without sulfites -- the most common
wine preservative -- many wines would spoil before ever reaching your local wine
shop. Sulfites are a naturally occurring part of the fermentation process, and
winemakers have used sulfur dioxide as a preservative in one form or another for
hundreds of years. Today a compound like potassium metabisulphite is added in
tiny amounts at more than one stage during the fermentation process, and it
releases sulfur dioxide that inhibits the growth of mold, vinegar-causing
bacteria, and other unwanted micro-organisms. It also prevents the wine from
oxidizing.
Red Wine Headache (RWH) is an
actual syndrome, but studies have shown that the cause isn’t sulfites. More
likely it’s histamines, naturally occurring compounds found in animals and
plants. “In wine, the amounts of histamine and tyramine are generally pretty
small, and by themselves wouldn’t cause any problems, but you have this
alcohol which inhibits the body’s defense system,” says Mark Daeschel of the
Department of Food Science and Technology at Oregon State University. “Ethanol
acts as an MAO inhibitor.” He said people who take MAO inhibitors (a class of
antidepressants) are warned not to ingest foods that have histamines, and that
should include red wine.
Some asthmatics have reactions
triggered by sulfites, although a researcher in the field says wine doesn’t
contain enough to be dangerous to most people. “The research I have seen shows
that reactions to sulfites are dose- related, and I have failed to find a find a
reaction below 250 parts per million,” said Dr. Keith Marton, chief medical
officer of Legacy Health System and clinical professor of medicine at Oregon
Health and Sciences University in Portland. The legal limit for U.S. wines is
350 parts per million; UC Davis studies show California wines average 80 ppm.
Marton adds: “There is at least one well-designed study
that showed that red wine drinkers had less asthma than non-wine drinkers.”
Still, asthmatics and others worried about sulfite can find wines with none
added such as Frey Vineyards in Redwood Valley. Winemaker Jonathan Frey admitted
that his winery has had “our ups and downs (making organic wine).”
“With modern winemaking equipment, I think it’s
possible to make a sulfite-free wine,” Frey says. “If you have healthy fruit
and get a clean fermentation, the wine is stable.” “To me, making wine
without sulfites is like climbing Mt. Everest without an oxygen mask,” said
Vinovation’s Smith. “People will say you’re crazy, but you might be able
to do it.“
Frey says, “We aren’t making wines for long-term
storage. We recommend that people drink our reds within five years of the
harvest.” And if there are any floaties in it, or in any of your wines at
home, relax. It’s not a problem.
THE QUICK AND DIRTY ON WHAT IS (OR HAS BEEN) IN YOUR
WINE A: These are tartrates (cream of tartar) and are harmless.
Tartrate crystals, a natural by-product of fermentation, can be removed by
winemakers who chill the wine (called cold stabilization) or filter out the
crystals. Some believe that filtration diminishes the wine’s character, so
they leave the wine unfiltered. If you don’t like the wine’s appearance,
decant it before service. Q: What about that sludge in the bottom of my glass? A: Wine sediment is made up of naturally occurring solids
that are harmless but can taste bitter. Like tartrate crystals, sediment
sometimes remains in bottled wine because the winemaker has chosen not to fine
or filter it. Again, decanting removes sediment. Q: I’m a vegan; how will I know if animal products like
egg whites, fish bladders, or gelatin have been used to make a particular wine? A: While only trace amounts, if any, of these additions
appear in the finished wine, strict vegetarians and those with religious
concerns still want to know if animal products were used in production. Wines
labeled “unfined” will not have any animal products in them. However, not
all unfined wines say so on the label, and fined wines generally don’t state
that on the label either. The only way to know is to call the winery and ask. Q: Are there non-animal fining agents? A: Yes, including bentonite, which is a type of clay, and
polyvinylpolypyrrolidone (PVPP), which is similar to ground-up nylon. Q: What are sulfites and why are they in wine? A: Sulfites are sulfur compounds found naturally on fresh
grapes and in all wines; winemakers can also add them to wines to inhibit the
growth of mold and vinegar-causing bacteria, and to prevent oxidation. Sulfites
play an important role in preserving wine’s freshness, yet are also a health
concern to those few who are allergic or sensitive to them. Wines without added
sulfites can be labeled as “sulfite-free” if the levels are under 10 parts per million.

E-Mail:
beekman@conversent.net